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Remediation of soil and groundwater contaminated with organic chemicals using stabilized nanoparticles

Zhengqing Cai, Xiao Zhao, Jun Duan, Dongye Zhao, Zhi Dang, Zhang Lin

《环境科学与工程前沿（英文）》 2020年 第14卷 第5期 doi: 10.1007/s11783-020-1263-8

摘要： Abstract ▪ Overviewed evolution and environmental applications of stabilized nanoparticles. ▪ Reviewed theories on particle stabilization for enhanced reactivity/deliverability. ▪ Examined various in situ remediation technologies based on stabilized nanoparticles. ▪ Summarized knowledge on transport of stabilized nanoparticles in porous media. ▪ Identified key knowledge gaps and future research needs on stabilized nanoparticles. Due to improved soil deliverability and high reactivity, stabilized nanoparticles have been studied for nearly two decades for in situ remediation of soil and groundwater contaminated with organic pollutants. While large amounts of bench- and field-scale experimental data have demonstrated the potential of the innovative technology, extensive research results have also unveiled various merits and constraints associated different soil characteristics, types of nanoparticles and particle stabilization techniques. Overall, this work aims to critically overview the fundamental principles on particle stabilization, and the evolution and some recent developments of stabilized nanoparticles for degradation of organic contaminants in soil and groundwater. The specific objectives are to: 1) overview fundamental mechanisms in nanoparticle stabilization; 2) summarize key applications of stabilized nanoparticles for in situ remediation of soil and groundwater contaminated by legacy and emerging organic chemicals; 3) update the latest knowledge on the transport and fate of stabilized nanoparticles; 4) examine the merits and constraints of stabilized nanoparticles in environmental remediation applications; and 5) identify the knowledge gaps and future research needs pertaining to stabilized nanoparticles for remediation of contaminated soil and groundwater. Per instructions of this invited special issue, this review is focused on contributions from our group (one of the pioneers in the subject field), which, however, is supplemented by important relevant works by others. The knowledge gained is expected to further advance the science and technology in the environmental applications of stabilized nanoparticles.

关键词： Stabilized nanoparticle     In-situ remediation     Organic contaminant     Soil remediation     Groundwater     Fate and transport    

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Mechanical properties of stabilized artificial organic soil

XU Riqing, GUO Yin, LIU Zengyong

《结构与土木工程前沿（英文）》 2008年 第2卷 第2期   页码 161-165 doi: 10.1007/s11709-008-0023-9

摘要： In order to study the influence of organic matter on the mechanical properties of stabilized soil and the effect of XGL2005 on stabilizing organic soil, unconfined compressive strength tests were carried out. Test results indicated that the strength of stabilized soil decreased in the form of a logarithmic function as the organic matter content increased. In contrast, the strength increased in the form of a power function as the content of the stabilization agent increased. The strength of cement stabilized organic soil was reinforced greatly by adding the stabilizer XGL2005. Based on the law obtained from the test, a strength prediction model was established by regression analysis. The model included the influence of the curing time, the content of the cement, the organic matter content and the stabilization agent on the strength of stabilized soil.

关键词： compressive strength     stabilized     stabilization     regression analysis     stabilizer XGL2005    

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Biopolymer-stabilized emulsions on the basis of interactions between β -lactoglobulin and ι -carrageenan

Qiaomei RU, Younghee CHO, Qingrong HUANG,

《化学科学与工程前沿（英文）》 2009年 第3卷 第4期   页码 399-406 doi: 10.1007/s11705-009-0253-y

摘要： -Carrageenan and -lactoglobulin (-lg) stabilized oil-in-water (O/W) emulsions, which can be used for the oral administration of bioactive but environmentally sensitive ingredients, have been successfully prepared. The effects of protein/polysaccharide ratios, total biopolymer concentration, environmental stress (thermal processing and sonication), and pH on the complex formation between -carrageenan and -lactoglobulin have been investigated. We found that -lactoglobulin and-carrageenan stabilized emulsions can be formed at pH values of 6.0, 4.0, and 3.4. However, the microstructures of emulsions stabilized by -lactoglobulin and -carrageenan was identified by optical microscopy, and it indicated that the emulsion prepared at pH 6.0 flocculated more extensively, while its hydrodynamic radius was much bigger than those prepared at pH 4.0 and 3.4. Regarding rheological properties, the emulsion of pH 6.0 showed a more solid-like behavior but with a lower viscosity than those of pH 4.0 and 3.4. The optimum concentration ranges for -lg and-carrageenan to form stable emulsions at pH 4.0 and 3.4 were 0.3wt-%―0.6wt-% and 0.4wt-%―0.7wt-%, respectively.
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High-precision gyro-stabilized control of a gear-driven platform with a floating gear tension device

《机械工程前沿（英文）》 2021年 第16卷 第3期   页码 487-503 doi: 10.1007/s11465-021-0635-5

摘要： This study presents an improved compound control algorithm that substantially enhances the anti-disturbance performance of a gear-drive gyro-stabilized platform with a floating gear tension device. The tension device can provide a self-adjustable preload to eliminate the gap in the meshing process. However, the weaker gear support stiffness and more complex meshing friction are also induced by the tension device, which deteriorates the control accuracy and the ability to keep the aim point of the optical sensors isolated from the platform motion. The modeling and compensation of the induced complex nonlinearities are technically challenging, especially when base motion exists. The aim of this research is to cope with the unmeasured disturbances as well as the uncertainties caused by the base lateral motion. First, the structural properties of the gear transmission and the friction-generating mechanism are analyzed, which classify the disturbances into two categories: Time-invariant and time-varying parts. Then, a proportional-integral controller is designed to eliminate the steady-state error caused by the time-invariant disturbance. A proportional multiple-integral-based state augmented Kalman filter is proposed to estimate and compensate for the time-varying disturbance that can be approximated as a polynomial function. The effectiveness of the proposed compound algorithm is demonstrated by comparative experiments on a gear-drive pointing system with a floating gear tension device, which shows a maximum 76% improvement in stabilization precision.

关键词： inertially stabilized platform     floating gear tension device     nonlinear friction     disturbance compensation     proportional multiple-integral observer    

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Characteristics of the stabilized/solidified municipal solid wastes incineration fly ash and the leaching

Yan SHAO,Haobo HOU,Guangxing WANG,Sha WAN,Min ZHOU

《环境科学与工程前沿（英文）》 2016年 第10卷 第1期   页码 192-200 doi: 10.1007/s11783-014-0719-0

摘要： Fly ash is a hazardous byproduct of municipal solid wastes incineration (MSWI). An alkali activated blast furnace slag-based cementitious material was used to stabilize/solidify the fly ash at experimental level. The characteristics of the stabilized/solidified fly ash, including metal leachability, mineralogical characteristics and the distributions of metals in matrices, were tested by toxic characteristic leaching procedure (TCLP), X-ray diffraction (XRD) and scanning electron microscopy-energy dispersive spectrometer (SEM-EDS) respectively. Continuous acid extraction was utilized to extract metal ions and characterize their leaching behavior. The stabilization/solidification procedure for MSWI fly ash demonstrates a strong fixing capacity for the metals by the formation of C-S-H phase, hydrated calcium aluminosilicate and ettringite. The stabilized/solidified fly ash shows a dense and homogeneous microstructure. Cr is mainly solidified in hydrated calcium aluminosilicate, C-S-H and ettringite phase through physical encapsulation, precipitation, adsorption or substitution mechanisms, and Pb is mainly solidified in C-S-H phase and absorbed in the Si-O structure.

关键词： municipal solid waste incineration (MSWI) fly ash     blast furnace slag     leaching behavior     Cr     Pb    

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Effect of polymer structures on electro-optical properties of polymer stabilized liquid crystal films

WANG Shoulian, HE Jie, ZENG Yu, YAN Bin, WANG Yinghan

《化学科学与工程前沿（英文）》 2008年 第2卷 第3期   页码 265-268 doi: 10.1007/s11705-008-0054-8

摘要： The polymer stabilized liquid crystal (PSLC) film is a relatively novel electro-optical material, which is generally obtained by dissolving a small amount of a bifunctional photoreactive monomer in a low molecular mass liquid crystal. In this paper, the PSLC films were prepared with photoreactive biphenyl methacrylate monomers by photopolymerization induced phase separation. The effects of liquid crystal concentration, curing time, monomer structures and alignment layer on the electro-optical properties of PSLC films were investigated. The results show that the transmittance in the OFF state () increased with the liquid crystal concentration, but the driving voltage decreased. was also influenced by the curing time. Furthermore, when polyimide was used as alignment layer, the films prepared from the bifunctional monomer shows a higher T, while those from the single functional monomer exhibited a deformed electro-optical curve due to the unsteady polymer networks.
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Structural characteristics of cement-stabilized soil bases with 3D finite element method

Yunfeng PENG, Yunlong HE,

《结构与土木工程前沿（英文）》 2009年 第3卷 第4期   页码 428-434 doi: 10.1007/s11709-009-0059-5

摘要： Cement-stabilized soil bases have been widely used in expressways due to its high strength, appropriate stiffness, good water resistance, and frost resistance. So far, the structural characteristics and mechanical behaviors of cement-stabilized soil bases were not investigated so much. In this paper, the 3D elastic-plastic finite element method (FEM) was used to analyze the mechanical behaviors and structural characteristics of cement-stabilized soil bases from construction to operation. The pavement filling and the traffic loading processes were simulated, and a contact model was used to simulate the contact behavior between each layer of the pavement. Considering the construction process, the structural characteristics and mechanical behaviors of cement-stabilized soil bases were studied under asphalt-concrete pavement conditions. Furthermore, the general rules of deformations and stresses in cement-stabilized soil bases under different conditions were discussed, and some suggestions were put forward for the design and construction of cement-stabilized soil bases.

关键词： different     strength     asphalt-concrete pavement     FEM     appropriate stiffness    

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Unconfined compressive strength prediction of soils stabilized using artificial neural networks and support

Alireza TABARSA, Nima LATIFI, Abdolreza OSOULI, Younes BAGHERI

《结构与土木工程前沿（英文）》 2021年 第15卷 第2期   页码 520-536 doi: 10.1007/s11709-021-0689-9

摘要： This study aims to improve the unconfined compressive strength of soils using additives as well as by predicting the strength behavior of stabilized soils using two artificial-intelligence-based models. The soils used in this study are stabilized using various combinations of cement, lime, and rice husk ash. To predict the results of unconfined compressive strength tests conducted on soils, a comprehensive laboratory dataset comprising 137 soil specimens treated with different combinations of cement, lime, and rice husk ash is used. Two artificial-intelligence-based models including artificial neural networks and support vector machines are used comparatively to predict the strength characteristics of soils treated with cement, lime, and rice husk ash under different conditions. The suggested models predicted the unconfined compressive strength of soils accurately and can be introduced as reliable predictive models in geotechnical engineering. This study demonstrates the better performance of support vector machines in predicting the strength of the investigated soils compared with artificial neural networks. The type of kernel function used in support vector machine models contributed positively to the performance of the proposed models. Moreover, based on sensitivity analysis results, it is discovered that cement and lime contents impose more prominent effects on the unconfined compressive strength values of the investigated soils compared with the other parameters.

关键词： unconfined compressive strength     artificial neural network     support vector machine     predictive models     regression    

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Performance of iron-air battery with iron nanoparticle-encapsulated C–N composite electrode

《能源前沿（英文）》 doi: 10.1007/s11708-023-0913-5

摘要： Highly efficient and stable iron electrodes are of great significant to the development of iron-air battery (IAB). In this paper, iron nanoparticle-encapsulated C–N composite (NanoFe@CN) was synthesized by pyrolysis using polyaniline as the C–N source. Electrochemical performance of the NanoFe@CN in different electrolytes (alkaline, neutral, and quasi-neutral) was investigated via cyclic voltammetry (CV). The IAB was assembled with NanoFe@CN as the anode and IrO2 + Pt/C as the cathode. The effects of different discharging/charging current densities and electrolytes on the battery performance were also studied. Neutral K2SO4 electrolyte can effectively suppress the passivation of iron electrode, and the battery showed a good cycling stability during 180 charging/discharging cycles. Compared to the pure nano-iron (NanoFe) battery, the NanoFe@CN battery has a more stable cycling stability either in KOH or NH4Cl + KCl electrolyte.

关键词： energy storage and conversion     metallic composites     nanocomposites     iron-air battery     iron anode    

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Effect of noble metal nanoparticle size on C–N bond cleavage performance in hydrodenitrogenation: a study

《化学科学与工程前沿（英文）》 2023年 第17卷 第12期   页码 1986-2000 doi: 10.1007/s11705-023-2337-5

摘要： Breakage of the C–N bond is a structure sensitive process, and the catalyst size significantly affects its activity. On the active metal nanoparticle scale, the role of catalyst size in C–N bond cleavage has not been clearly elucidated. So, Ru catalysts with variable nanoparticle sizes were obtained by modulating the reduction temperature, and the catalytic activity was evaluated using 1,2,3,4-tetrahydroquinoline and o-propylaniline with different C–N bond hybridization patterns as reactants. Results showed a 13 times higher reaction rate for sp3-hybridized C–N bond cleavage than sp2-hybridized C–N bond cleavage, while the reaction rate tended to increase first and then decrease as the catalyst nanoparticle size increased. Different concentrations of terrace, step, and corner sites were found in different sizes of Ru nanoparticles. The relationship between catalytic site variation and C–N bond cleavage activity was further investigated by calculating the turnover frequency values for each site. This analysis indicates that the variation of different sites on the catalyst is the intrinsic factor of the size dependence of C–N bond cleavage activity, and the step atoms are the active sites for the C–N bond cleavage. When Ru nanoparticles are smaller than 1.9 nm, they have a strong adsorption effect on the reactants, which will affect the catalytic performance of the Ru catalyst. Furthermore, these findings were also confirmed on other metallic Pd/Pt catalysts. The role of step sites in C–N bond cleavage was proposed using the density function theory calculations. The reactants have stronger adsorption energies on the step atoms, and step atoms have d-band center nearer to the Fermi level. In this case, the interaction with the reactant is stronger, which is beneficial for activating the C–N bond of the reactant.

关键词： sp3/sp2-hybridized C–N bond     noble metal nanoparticle     catalytic active site     turnover frequency     DFT    

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Iron oxide nanoparticle-based theranostics for cancer imaging and therapy

Xiaoqing REN,Hongwei CHEN,Victor YANG,Duxin SUN

《化学科学与工程前沿（英文）》 2014年 第8卷 第3期   页码 253-264 doi: 10.1007/s11705-014-1425-y

摘要： Theranostic platform, which is equipped with both diagnostic and therapeutic functions, is a promising approach in cancer treatment. From various nanotheranostics studied, iron oxide nanoparticles have advantages since IONPs have good biocompatibility and spatial imaging capability. This review is focused on the IONP-based nanotheranostics for cancer imaging and treatment. The most recent progress for applications of IONP nanotheranostics is summarized, which includes IONP-based diagnosis, magnetic resonance imaging (MRI), multimodal imaging, chemotherapy, hyperthermal therapy, photodynamic therapy, and gene delivery. Future perspectives and challenges are also outlined for the potential development of IONP based theranostics in clinical use.

关键词： theranostics     iron oxide nanoparticles     MRI     drug delivery     photothermal therapy     photodynamic therapy    

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Nanoparticle-enhanced coolants in machining: mechanism, application, and prospects

《机械工程前沿（英文）》 2023年 第18卷 第4期 doi: 10.1007/s11465-023-0769-8

摘要： Nanoparticle-enhanced coolants (NPECs) are increasingly used in minimum quantity lubrication (MQL) machining as a green lubricant to replace conventional cutting fluids to meet the urgent need for carbon emissions and achieve sustainable manufacturing. However, the thermophysical properties of NPEC during processing remain unclear, making it difficult to provide precise guidance and selection principles for industrial applications. Therefore, this paper reviews the action mechanism, processing properties, and future development directions of NPEC. First, the laws of influence of nano-enhanced phases and base fluids on the processing performance are revealed, and the dispersion stabilization mechanism of NPEC in the preparation process is elaborated. Then, the unique molecular structure and physical properties of NPECs are combined to elucidate their unique mechanisms of heat transfer, penetration, and anti-friction effects. Furthermore, the effect of NPECs is investigated on the basis of their excellent lubricating and cooling properties by comprehensively and quantitatively evaluating the material removal characteristics during machining in turning, milling, and grinding applications. Results showed that turning of Ti‒6Al‒4V with multi-walled carbon nanotube NPECs with a volume fraction of 0.2% resulted in a 34% reduction in tool wear, an average decrease in cutting force of 28%, and a 7% decrease in surface roughness Ra, compared with the conventional flood process. Finally, research gaps and future directions for further applications of NPECs in the industry are presented.

关键词： nanoparticle-enhanced coolant     minimum quantity lubrication     biolubricant     thermophysical properties     turning     milling     grinding    

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Cobalt nanoparticle decorated N-doped carbons derived from a cobalt covalent organic framework for oxygen

《化学科学与工程前沿（英文）》 2021年 第15卷 第6期   页码 1550-1560 doi: 10.1007/s11705-021-2104-4

摘要： The low cost and highly efficient construction of electrocatalysts has attracted significant attention owing to the use of clean and sustainable energy technologies. In this work, cobalt nanoparticle decorated N-doped carbons (Co@NC) are synthesized by the pyrolysis of a cobalt covalent organic framework under an inert atmosphere. The Co@NC demonstrates improved electrocatalytic capabilities compared to N-doped carbon without the addition of Co nanoparticles, indicating the important role of cobalt. The well-dispersed active sites (Co-Nx) and the synergistic effect between the carbon matrix and Co nanoparticles greatly enhance the electrocatalytic activity for the oxygen reduction reaction. In addition, the Co content has a significant effect on the catalytic activity. The resulting Co@NC-0.86 exhibits a superb electrocatalytic activity for the oxygen reduction reaction in an alkaline electrolyte in terms of the onset potential (0.90 V), half-wave potential (0.80 V) and the limiting current density (4.84 mA·cm–2), and a high selectivity, as well as a strong methanol tolerance and superior durability, these results are comparable to those of the Pt/C catalyst. Furthermore, the superior bifunctional activity of Co@NC-0.86 was also confirmed in a home-built Zn-air battery, signifying the possibility for application in electrode materials and in current energy conversion and storage devices.

关键词： cobalt embedment     N-doped carbons     covalent organic framework     oxygen reduction     Zn-air battery    

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hydrogenation of halogenated nitrobenzenes over metal–organic-framework-derived ultra-dispersed Ni stabilized

《化学科学与工程前沿（英文）》 2022年 第16卷 第12期   页码 1782-1792 doi: 10.1007/s11705-022-2220-9

摘要： Ultra-dispersed Ni nanoparticles (7.5 nm) on nitrogen-doped carbon nanoneedles (Ni@NCNs) were prepared by simple pyrolysis of Ni-based metal–organic-framework for selective hydrogenation of halogenated nitrobenzenes to corresponding anilines. Two different crystallization methods (stirring and static) were compared and the optimal pyrolysis temperature was explored. Ni@NCNs were systematically characterized by wide analytical techniques. In the hydrogenation of p-chloronitrobenzene, Ni@NCNs-600 (pyrolyzed at 600 °C) exhibited extraordinarily high performance with 77.9 h–1 catalytic productivity and > 99% p-chloroaniline selectivity at full p-chloronitrobenzene conversion under mild conditions (90 °C, 1.5 MPa H2), showing obvious superiority compared with reported Ni-based catalysts. Notably, the reaction smoothly proceeded at room temperature with full conversion and > 99% selectivity. Moreover, Ni@NCNs-600 afforded good tolerance to various nitroarenes substituted by sensitive groups (halogen, nitrile, keto, carboxylic, etc.), and could be easily recycled by magnetic separation and reused for 5 times without deactivation. The adsorption tests showed that the preferential adsorption of –NO2 on the catalyst can restrain the dehalogenation of p-chloronitrobenzene, thus achieving high p-chloroaniline selectivity. While the high activity can be attributed to high Ni dispersion, special morphology, and rich pore structure of the catalyst.

关键词： halogenated nitrobenzenes     room-temperature hydrogenation     Ni nanoparticles     nitrogen-doped carbon nanoneedles     metal–organic-framework    

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Crushed rocks stabilized with organosilane and lignosulfonate in pavement unbound layers: Repeated load

Diego Maria BARBIERI, Inge HOFF, Chun-Hsing HO

《结构与土木工程前沿（英文）》 2021年 第15卷 第2期   页码 412-424 doi: 10.1007/s11709-021-0700-5

摘要： The creation of the new “Ferry-Free Coastal Highway Route E39” in southwest Norway entails the production of a remarkable quantity of crushed rocks. These resources could be beneficially employed as aggregates in the unbound courses of the highway itself or other road pavements present nearby. Two innovative stabilizing agents, organosilane and lignosulfonate, can significantly enhance the key properties, namely, resilient modulus and resistance against permanent deformation, of the aggregates that are excessively weak in their natural state. The beneficial effect offered by the additives was thoroughly evaluated by performing repeated load triaxial tests. The study adopted the most common numerical models to describe these two key mechanical properties. The increase in the resilient modulus and reduction in the accumulated vertical permanent deformation show the beneficial impact of the additives. Furthermore, a finite element model was created to simulate the repeated load triaxial test by implementing nonlinear elastic and plastic constitutive relationships.

关键词： organosilane     lignosulfonate     crushed rocks     pavement unbound layers     repeated load triaxial test     finite element analysis    

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标题 作者 时间 类型 操作

Remediation of soil and groundwater contaminated with organic chemicals using stabilized nanoparticles

Zhengqing Cai, Xiao Zhao, Jun Duan, Dongye Zhao, Zhi Dang, Zhang Lin

期刊论文

Mechanical properties of stabilized artificial organic soil

XU Riqing, GUO Yin, LIU Zengyong

期刊论文

Biopolymer-stabilized emulsions on the basis of interactions between β -lactoglobulin and ι -carrageenan

Qiaomei RU, Younghee CHO, Qingrong HUANG,

期刊论文

High-precision gyro-stabilized control of a gear-driven platform with a floating gear tension device

期刊论文

Characteristics of the stabilized/solidified municipal solid wastes incineration fly ash and the leaching

Yan SHAO,Haobo HOU,Guangxing WANG,Sha WAN,Min ZHOU

期刊论文

Effect of polymer structures on electro-optical properties of polymer stabilized liquid crystal films

WANG Shoulian, HE Jie, ZENG Yu, YAN Bin, WANG Yinghan

期刊论文

Structural characteristics of cement-stabilized soil bases with 3D finite element method

Yunfeng PENG, Yunlong HE,

期刊论文

Unconfined compressive strength prediction of soils stabilized using artificial neural networks and support

Alireza TABARSA, Nima LATIFI, Abdolreza OSOULI, Younes BAGHERI

期刊论文

Performance of iron-air battery with iron nanoparticle-encapsulated C–N composite electrode

期刊论文

Effect of noble metal nanoparticle size on C–N bond cleavage performance in hydrodenitrogenation: a study

期刊论文

Iron oxide nanoparticle-based theranostics for cancer imaging and therapy

Xiaoqing REN,Hongwei CHEN,Victor YANG,Duxin SUN

期刊论文

Nanoparticle-enhanced coolants in machining: mechanism, application, and prospects

期刊论文

Cobalt nanoparticle decorated N-doped carbons derived from a cobalt covalent organic framework for oxygen

期刊论文

hydrogenation of halogenated nitrobenzenes over metal–organic-framework-derived ultra-dispersed Ni stabilized

期刊论文

Crushed rocks stabilized with organosilane and lignosulfonate in pavement unbound layers: Repeated load

Diego Maria BARBIERI, Inge HOFF, Chun-Hsing HO

期刊论文